Publication: Structure development and viscoelastic properties in silane-crosslinked ethylene-octene copolymer
Issued Date
2008-08-15
Resource Type
ISSN
10974628
00218995
00218995
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2-s2.0-55849093596
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Mahidol University
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SCOPUS
Bibliographic Citation
Journal of Applied Polymer Science. Vol.109, No.4 (2008), 2347-2353
Suggested Citation
Walailuck Kamphunthong, Kalyanee Sirisinha Structure development and viscoelastic properties in silane-crosslinked ethylene-octene copolymer. Journal of Applied Polymer Science. Vol.109, No.4 (2008), 2347-2353. doi:10.1002/app.28302 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/19069
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Title
Structure development and viscoelastic properties in silane-crosslinked ethylene-octene copolymer
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Abstract
The development of structure and viscoelastic properties during silane crosslink reaction in metallocene ethylene-octene copolymer has been investigated. Using attenuated and transmission infrared spectroscopy, the concentrations of certain functional groups and change in sample thickness were monitored, giving the information on the progress of crosslink reaction. The evolution of crosslink content and viscoelastic properties was analyzed using a parallel-plate rheometer. The results showed that crosslinking process started with the hydrolyzation of methoxy groups in the near-surface layer, proceeding in a diffusion manner. At this stage no silanol groups could be detected, revealing that the condensation occurred promptly after hydrolyzation. The internal crosslink could not begin until there are sufficient water molecules in the surrounding. A water by-product from the condensation reaction played an essential part in the center region. The rheological data showed a reduction in magnitude of creep compliance. As the reaction proceeded, more networks took place within an existing gel. The materials, then, acted more like elastic and exhibited an improvement in ability for recovery process. The immobilization of chain segments, due to the presence of tight network, disallowed conformations necessary for crosslink reaction and a certain amount of hydrolyzable groups and silanol groups remained after a long crosslinking process. © 2008 Wiley Periodicals, Inc.