Publication:
Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters

Issued Date

1989-01-01

Resource Type

Article

ISSN

00404039

DOI

10.1016/S0040-4039(01)80677-8

Other identifier(s)

2-s2.0-0024359306

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron Letters. Vol.30, No.29 (1989), 3857-3860

Suggested Citation

C. Mahidol, C. Thebtaranonth, Y. Thebtaranonth, C. Yenjai Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters. Tetrahedron Letters. Vol.30, No.29 (1989), 3857-3860. doi:10.1016/S0040-4039(01)80677-8 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/15719

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Title

Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters

Author(s)

C. Mahidol
 C. Thebtaranonth
 Y. Thebtaranonth
 C. Yenjai

Other Contributor(s)

Mahidol University

Abstract

[±]-Deepoxy-4,5-didehydromethylenomycin A methyl ester 8 and [±] -methylenomycin A methyl ester 9 are synthesized from anthracene adduct 2 via a common intermediate 13. Flash vacuum pyrolysis of adduct 13 gives 8, while stereospecific epoxidation of 13 followed by pyrolysis yields 9. © 1989.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/15719

Collections

Scopus 1969-1990