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Self-assembled Cu(II) cluster from aerobic oxidation of Cu(I)Br with tris(triazolyl)methanol

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dc.contributor.authorNonglak Khunoaden_US
dc.contributor.authorNuttaporn Krittametapornen_US
dc.contributor.authorSoraya Pornsuwanen_US
dc.contributor.authorPalangpon Kongsaereeen_US
dc.contributor.authorSerhiy Demeshkoen_US
dc.contributor.authorPreeyanuch Sangtrirutnugulen_US
dc.contributor.otherUniversität Göttingenen_US
dc.contributor.otherMahidol Universityen_US
dc.date.accessioned2020-01-27T08:14:09Z
dc.date.available2020-01-27T08:14:09Z
dc.date.issued2019-03-24en_US
dc.description.abstract© 2019 Elsevier B.V. Treatment of tris(4-benzyl-1,2,3-triazolyl)methanol (Htbtm) with CuIBr in refluxed CH2Cl2 under aerobic conditions afforded the hexanuclear CuII complexes with the formula Cu6(µ3-O⋯H⋯O-µ3)(µ-tbtm-к3-O,N3,N3′)3(µ-Br)6. The crystal structure reveals two Cu3(µ-Br)3(µ3-O) units linked by three deprotonated tbtm ligands and a proton. Magnetic studies of the hexanuclear CuII cluster show a strong overall antiferromagnetic behavior with a dominant coupling interaction between CuII⋯CuII ions of different Cu3(µBr)3(µ3-O) units.en_US
dc.identifier.citationInorganica Chimica Acta. Vol.488, (2019), 141-144en_US
dc.identifier.doi10.1016/j.ica.2019.01.021en_US
dc.identifier.issn00201693en_US
dc.identifier.other2-s2.0-85060203402en_US
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/20.500.14594/50574
dc.rightsMahidol Universityen_US
dc.rights.holderSCOPUSen_US
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85060203402&origin=inwarden_US
dc.subjectChemistryen_US
dc.subjectMaterials Scienceen_US
dc.titleSelf-assembled Cu(II) cluster from aerobic oxidation of Cu(I)Br with tris(triazolyl)methanolen_US
dc.typeArticleen_US
dspace.entity.typePublication
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85060203402&origin=inwarden_US

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