Publication:
Organopromoted Direct Synthesis of 1,1-Diphenyl-3-arylindanes via Formal [3+2] Cycloadditions of Triphenylcarbenium Tetrafluoroborate with Styrenes

Issued Date

2016-12-01

Resource Type

Review

ISSN

14372096
09365214

DOI

10.1055/s-0036-1588302

Other identifier(s)

2-s2.0-84984850896

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Synlett. Vol.27, No.19 (2016), 2689-2694

Suggested Citation

Nakin Surapanich, Patcharin Chaisuwan, Chutima Kuhakarn, Vichai Reutrakul Organopromoted Direct Synthesis of 1,1-Diphenyl-3-arylindanes via Formal [3+2] Cycloadditions of Triphenylcarbenium Tetrafluoroborate with Styrenes. Synlett. Vol.27, No.19 (2016), 2689-2694. doi:10.1055/s-0036-1588302 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/43377

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Title

Organopromoted Direct Synthesis of 1,1-Diphenyl-3-arylindanes via Formal [3+2] Cycloadditions of Triphenylcarbenium Tetrafluoroborate with Styrenes

Author(s)

Nakin Surapanich
 Patcharin Chaisuwan
 Chutima Kuhakarn
 Vichai Reutrakul

Other Contributor(s)

Rajabhat Rajanagarindra University
 Suranaree University of Technology
 Mahidol University

Abstract

© Georg Thieme Verlag Stuttgart.New York-Synlett 2016. A formal [3+2] cycloaddition of triphenylcarbenium tetrafluoroborate with structurally different styrene derivatives has been developed. A combination of benzophenone and Et3N is key for promoting a formal [3+2] cycloaddition of triphenylcarbenium tetrafluoroborate with styrenes affording 1,1-diphenyl-3-arylindanes in moderate to good yields. The reaction mechanism of this transformation is also discussed.

Keyword(s)

Chemistry

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/43377

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Scopus 2016-2017