Publication: Synthesis of high-molecular-weight poly(ε-caprolactone) catalyzed by highly active bis(amidinate) tin(ii) complexes
dc.contributor.author | Khamphee Phomphrai | en_US |
dc.contributor.author | Chatyapha Pongchan-O | en_US |
dc.contributor.author | Wipavee Thumrongpatanaraks | en_US |
dc.contributor.author | Preeyanuch Sangtrirutnugul | en_US |
dc.contributor.author | Palangpon Kongsaeree | en_US |
dc.contributor.author | Manat Pohmakotr | en_US |
dc.contributor.other | Mahidol University | en_US |
dc.date.accessioned | 2018-05-03T08:07:47Z | |
dc.date.available | 2018-05-03T08:07:47Z | |
dc.date.issued | 2011-03-14 | en_US |
dc.description.abstract | A series of bis(amidinate) tin(ii) complexes is synthesized and shown to rapidly polymerize ε-caprolactone (ε-CL) in the presence and absence of benzyl alcohol giving high-molecular-weight poly(ε-CL) (M n up to 160,600 Da). Ligands having electron donating groups were found to accelerate the polymerization by making the complex more nucleophilic. © 2011 The Royal Society of Chemistry. | en_US |
dc.identifier.citation | Dalton Transactions. Vol.40, No.10 (2011), 2157-2159 | en_US |
dc.identifier.doi | 10.1039/c0dt01050b | en_US |
dc.identifier.issn | 14779234 | en_US |
dc.identifier.issn | 14779226 | en_US |
dc.identifier.other | 2-s2.0-79951928361 | en_US |
dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/20.500.14594/11724 | |
dc.rights | Mahidol University | en_US |
dc.rights.holder | SCOPUS | en_US |
dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=79951928361&origin=inward | en_US |
dc.subject | Chemistry | en_US |
dc.title | Synthesis of high-molecular-weight poly(ε-caprolactone) catalyzed by highly active bis(amidinate) tin(ii) complexes | en_US |
dc.type | Article | en_US |
dspace.entity.type | Publication | |
mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=79951928361&origin=inward | en_US |