Publication: Novel approaches for controlling stage structure of metal chloride-graphite intercalation compounds
Issued Date
2002-01-01
Resource Type
ISSN
08842914
Other identifier(s)
2-s2.0-0036968319
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Mahidol University
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SCOPUS
Bibliographic Citation
Journal of Materials Research. Vol.17, No.12 (2002), 3190-3192
Suggested Citation
H. Shioyama, M. B.H.M. Saman, A. Sanpanich Novel approaches for controlling stage structure of metal chloride-graphite intercalation compounds. Journal of Materials Research. Vol.17, No.12 (2002), 3190-3192. doi:10.1557/JMR.2002.0461 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/20163
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Title
Novel approaches for controlling stage structure of metal chloride-graphite intercalation compounds
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Abstract
Intercalation of EuCl3TbCl3, and AlCl3into graphite was carried out in the presence of chlorine. The observation of products by x-ray diffraction showed that the extent of chloride intercalation could be controlled through adjustment of the pressure of chlorine; increasing pressure tended to increase the extent of intercalation. In the case of EuCl3, the extent of intercalation varied to show a stage transition. In contrast, TbCl3intercalation gave a mixture of stage 2 or stage 4 graphite intercalation compound (GIC) and remaining graphite, where the extent of intercalation is revealed by the ratio of GIC to graphite. With respect to AlCl3intercalation, although the preparation of stage 1, 2, and 4 GICs was successful, stage 3 and 5 GICs could not be obtained.