Publication:
α-(Phenylthio)cyclopropylation of carbonyl compounds: Preparation of α-cyclopropyl ketones

Issued Date

1997-09-22

Resource Type

Article

ISSN

00404039

DOI

10.1016/S0040-4039(97)01546-3

Other identifier(s)

2-s2.0-0030821569

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron Letters. Vol.38, No.38 (1997), 6759-6762

Suggested Citation

Manat Pohmakotr, Jirakorn Thisayukta α-(Phenylthio)cyclopropylation of carbonyl compounds: Preparation of α-cyclopropyl ketones. Tetrahedron Letters. Vol.38, No.38 (1997), 6759-6762. doi:10.1016/S0040-4039(97)01546-3 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/17880

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Title

α-(Phenylthio)cyclopropylation of carbonyl compounds: Preparation of α-cyclopropyl ketones

Author(s)

Manat Pohmakotr
 Jirakorn Thisayukta

Other Contributor(s)

Mahidol University

Abstract

α-Chloro-α-(phenylthio)cyclopropane and α-acetoxy-α-(phenylthio)cyclopropane were found to react with the silyl enol ethers of some ketones in the presence of Lewis acid in dichloromethane to provide α-(phenylthio)cyclopropyl ketones, which were subjected to reduction with Ra-Ni to give the corresponding α-cyclopropyl ketones.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/17880

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Scopus 1991-2000