Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
Journal of the Chemical Society, Chemical Communications. No.19 (1985), 1323-1324
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Tsuyoshi Habe, Mikio Shimada, Tadashi Okamoto, Bhinyo Panijpan, Takayoshi Higuchi Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase. Journal of the Chemical Society, Chemical Communications. No.19 (1985), 1323-1324. doi:10.1039/C39850001323 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/30756
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Incorporation of dioxygen into the hydroxylated product during the C-C single bond cleavage of 1,2-bis(p-methoxyphenyl)propane-1,3-diol catalysed by hemin. A novel model system for the hemoprotein ligninase
Oxidation of the lignin model compound 1,2-bis(p-methoxyphenyl)propane-1,3- diol (1) catalysed by hemin in the presence of t-butyl hydroperoxide and18O2yielded p-methoxyphenylethane-1,2-diol (2) with 83%18O incorporation into the newly formed hydroxy group and p-anisaldehyde (3) as the initial Cα-Cβbond cleavage products.
