Publication:
Total synthesis of 6-deoxyclitoriacetal isolated from Stemona collinsae Craib.

Issued Date

2006-08-14

Resource Type

Article

ISSN

00404039

DOI

10.1016/j.tetlet.2006.05.188

Other identifier(s)

2-s2.0-33745726167

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron Letters. Vol.47, No.33 (2006), 5989-5991

Suggested Citation

Prapas Khorphueng, Jumreang Tummatorn, Amorn Petsom, Richard J.K. Taylor, Sophon Roengsumran Total synthesis of 6-deoxyclitoriacetal isolated from Stemona collinsae Craib.. Tetrahedron Letters. Vol.47, No.33 (2006), 5989-5991. doi:10.1016/j.tetlet.2006.05.188 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/22993

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Title

Total synthesis of 6-deoxyclitoriacetal isolated from Stemona collinsae Craib.

Author(s)

Prapas Khorphueng
 Jumreang Tummatorn
 Amorn Petsom
 Richard J.K. Taylor
 Sophon Roengsumran

Other Contributor(s)

Mahidol University
 University of York

Abstract

A total synthesis of the rotenoid, 6-deoxyclitoriacetal, a cytotoxic natural product, was successfully achieved by using platinum-catalysed hydroarylation, Sharpless asymmetric dihydroxylation, regioselective IBX diol oxidation and stereoselective intramolecular keto-aldehyde pinacol coupling as the key steps. © 2006 Elsevier Ltd. All rights reserved.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

Availability

URI

https://repository.li.mahidol.ac.th/handle/123456789/22993

Collections

Scopus 2006-2010