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Synthesis and isolation of non-chromophore cage-rearranged silsesquioxanes from base-catalyzed reactions

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dc.contributor.authorSasikarn Hanprasiten_US
dc.contributor.authorNuttanee Tungkijanansinen_US
dc.contributor.authorArisa Prompawilaien_US
dc.contributor.authorSupattra Eangpayungen_US
dc.contributor.authorVuthichai Ervithayasupornen_US
dc.contributor.otherMahidol Universityen_US
dc.date.accessioned2018-12-11T02:35:21Z
dc.date.accessioned2019-03-14T08:04:28Z
dc.date.available2018-12-11T02:35:21Z
dc.date.available2019-03-14T08:04:28Z
dc.date.issued2016-01-01en_US
dc.description.abstract© 2016 Royal Society of Chemistry. The nucleophilicity of both ortho- and meta-nitrophenolate anions is strong enough to give substituted products, but their basicity also facilitates cage-rearrangement reactions in polyhedral oligomeric silsesquioxanes (POSS). Anions having a stronger basicity, but weaker nucleophilicity, such as CO32-, gave products only from cage-rearrangement, with the cage expansion products being isolable in multi-gram quantities using conventional column chromatography.en_US
dc.identifier.citationDalton Transactions. Vol.45, No.41 (2016), 16117-16120en_US
dc.identifier.doi10.1039/c6dt02585den_US
dc.identifier.issn14779234en_US
dc.identifier.issn14779226en_US
dc.identifier.other2-s2.0-84992179853en_US
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/123456789/43405
dc.rightsMahidol Universityen_US
dc.rights.holderSCOPUSen_US
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84992179853&origin=inwarden_US
dc.subjectChemistryen_US
dc.titleSynthesis and isolation of non-chromophore cage-rearranged silsesquioxanes from base-catalyzed reactionsen_US
dc.typeArticleen_US
dspace.entity.typePublication
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84992179853&origin=inwarden_US

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