Publication: Effect of Compatibilizers on Mechanical Properties and Morphology of In-Situ Composite Film of Thermotropic Liquid Crystalline Polymer/Polypropylene
Issued Date
1999-01-01
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ISSN
00323888
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2-s2.0-0033074941
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Mahidol University
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SCOPUS
Bibliographic Citation
Polymer Engineering and Science. Vol.39, No.2 (1999), 312-320
Suggested Citation
Sauvarop Bualek-Limcharoen, Jareerat Samran, Taweechai Amornsakchai, Wiriya Meesiri Effect of Compatibilizers on Mechanical Properties and Morphology of In-Situ Composite Film of Thermotropic Liquid Crystalline Polymer/Polypropylene. Polymer Engineering and Science. Vol.39, No.2 (1999), 312-320. doi:10.1002/pen.11417 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/25385
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Title
Effect of Compatibilizers on Mechanical Properties and Morphology of In-Situ Composite Film of Thermotropic Liquid Crystalline Polymer/Polypropylene
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Abstract
An in-situ composite film of a thermotropic liquid crystalline polymer (LC3000)/ polypropylene (TLCP/PP) was produced using the extrusion cast film technique. The compatibilizing effect of thermoplastic elastomers, styrene-ethylene butylene-styrene (SEBS), maleic anhydride grafted SEBS (MA-SEBS), and maleic anhydride grafted polypropylene (MA-PP) on the mechanical properties and morphology of the TLCP/PP composite films was investigated. It was found that SEBS provided a higher value of tensile modulus than MA-SEBS, which in turn was higher than MA-PP, despite the expected stronger interaction between the MA chain and TLCP. The observation of the morphology under optical and scanning electron microscopes suggested that all three compatibilizers helped improve the dispersion of the TLCP fibers and increased the fiber aspect ratio to a different extent. The fractured surface of the specimens showed more fiber breakage than pull-out when a compatibilizer was added, which suggested the improvement of interfacial adhesion. The surface roughness of fibers with an added elastomeric compatibilizer may also provide mechanical interlocking at the interface. It is suggested that the increase in the viscosity ratio of TLCP/PP due to the added elastomeric compatibilizer, SEBS and MA-SEBS, compared with the thermoplastic compatibilizer, MA-PP, is more effective in improving the composite mechanical properties.