Publication:
Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

Issued Date

2015-08-18

Resource Type

Article

ISSN

1364548X
13597345

DOI

10.1039/c5cc04432d

Other identifier(s)

2-s2.0-84938247919

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Chemical Communications. Vol.51, No.64 (2015), 12724-12727

Suggested Citation

Sangita Karanjit, Atchaleeya Jinasan, Ekasith Samsook, Raghu N. Dhital, Kenichi Motomiya, Yoshinori Sato, Kazuyuki Tohji, Hidehiro Sakurai Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides. Chemical Communications. Vol.51, No.64 (2015), 12724-12727. doi:10.1039/c5cc04432d Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/35695

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Title

Significant stabilization of palladium by gold in the bimetallic nanocatalyst leading to an enhanced activity in the hydrodechlorination of aryl chlorides

Author(s)

Sangita Karanjit
 Atchaleeya Jinasan
 Ekasith Samsook
 Raghu N. Dhital
 Kenichi Motomiya
 Yoshinori Sato
 Kazuyuki Tohji
 Hidehiro Sakurai

Other Contributor(s)

Osaka University
 Mahidol University
 Tohoku University
 Interdisciplinary Cluster for Cutting Edge Research
 Japan Science and Technology Agency
 Shinshu University

Abstract

© The Royal Society of Chemistry 2015. The stabilization effect of Au towards Pd changed the reactivity of Pd in Au/Pd bimetallic nanoclusters, altering the reaction mechanism from homogeneous to heterogeneous in dechlorination reaction of aryl chlorides. This phenomenon was illustrated by the observed enhancement of the rate of reaction by in situ generated Au-rich bimetallic Au/Pd nanoclusters.

Keyword(s)

Chemical Engineering
 Chemistry
 Materials Science

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/35695

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Scopus 2011-2015