Publication:
Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones

Issued Date

2007-07-06

Resource Type

Article

ISSN

00223263

DOI

10.1021/jo0705566

Other identifier(s)

2-s2.0-34447334803

Rights

Mahidol University

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SCOPUS

Bibliographic Citation

Journal of Organic Chemistry. Vol.72, No.14 (2007), 5418-5420

Suggested Citation

Manat Pohmakotr, Sirinporn Thamapipol, Patoomratana Tuchinda, Samran Prabpai, Palangpon Kongsaeree, Vichai Reutrakul Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones. Journal of Organic Chemistry. Vol.72, No.14 (2007), 5418-5420. doi:10.1021/jo0705566 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/24344

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Title

Morita-Baylis-Hillman reaction of masked 5-alkylidene-2-cyclopentenones: General entry to 5-alkylidene-2-(hydroxyalkyl)-2-cyclopentenones

Author(s)

Manat Pohmakotr
 Sirinporn Thamapipol
 Patoomratana Tuchinda
 Samran Prabpai
 Palangpon Kongsaeree
 Vichai Reutrakul

Other Contributor(s)

Mahidol University

Abstract

(Chemical Equation Presented) The reaction of masked 5-alkylidene-2- cyclopentenones with aldehydes catalyzed by tributylphosphine in the presence of phenol provided the corresponding Morita-Baylis-Hillman adducts, which were subjected to flash vacuum pyrolysis to afford 5-alkylidene-2-(hydroxyalkyl)-2- cyclopentenones. © 2007 American Chemical Society.

Keyword(s)

Chemistry

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URI

https://repository.li.mahidol.ac.th/handle/123456789/24344

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Scopus 2006-2010