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Intramolecular acylation of α-sulfinyl carbanions with masked α,β-unsaturated esters: a general strategy to 5-alkylidene-2-cyclopentenones

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dc.contributor.authorManat Pohmakotren_US
dc.contributor.authorSirinporn Thamapipolen_US
dc.contributor.authorPatoomratana Tuchindaen_US
dc.contributor.authorVichai Reutrakulen_US
dc.contributor.otherMahidol Universityen_US
dc.date.accessioned2018-08-24T01:43:13Z
dc.date.available2018-08-24T01:43:13Z
dc.date.issued2007-02-19en_US
dc.description.abstractA general method for the preparation of 5-alkylidene-2-cyclopentenones and their 2-phenylsulfanyl substituted derivatives, involving the intramolecular acylation of α-sulfinyl carbanions with cyclopentadiene-α,β-unsaturated esters as the key reaction followed by flash vacuum pyrolysis, is described. The reactions start from readily available Diels-Alder adducts, synthons of α-carbanions of α,β-unsaturated esters. © 2006 Elsevier Ltd. All rights reserved.en_US
dc.identifier.citationTetrahedron. Vol.63, No.8 (2007), 1806-1820en_US
dc.identifier.doi10.1016/j.tet.2006.12.036en_US
dc.identifier.issn00404020en_US
dc.identifier.other2-s2.0-33846238520en_US
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/20.500.14594/24246
dc.rightsMahidol Universityen_US
dc.rights.holderSCOPUSen_US
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33846238520&origin=inwarden_US
dc.subjectBiochemistry, Genetics and Molecular Biologyen_US
dc.subjectChemistryen_US
dc.subjectPharmacology, Toxicology and Pharmaceuticsen_US
dc.titleIntramolecular acylation of α-sulfinyl carbanions with masked α,β-unsaturated esters: a general strategy to 5-alkylidene-2-cyclopentenonesen_US
dc.typeArticleen_US
dspace.entity.typePublication
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33846238520&origin=inwarden_US

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