Publication:
Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes

Issued Date

2018-01-01

Resource Type

Article

ISSN

14770520

DOI

10.1039/C8OB02338G

Other identifier(s)

2-s2.0-85056520766

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Organic and Biomolecular Chemistry. Vol.16, No.44 (2018), 8553-8558

Suggested Citation

Onnicha Khaikate, Jatuporn Meesin, Manat Pohmakotr, Vichai Reutrakul, Pawaret Leowanawat, Darunee Soorukram, Chutima Kuhakarn Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes. Organic and Biomolecular Chemistry. Vol.16, No.44 (2018), 8553-8558. doi:10.1039/C8OB02338G Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/45272

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Title

Sulfinates and thiocyanates triggered 6-endo cyclization of o-alkynylisocyanobenzenes

Author(s)

Onnicha Khaikate
 Jatuporn Meesin
 Manat Pohmakotr
 Vichai Reutrakul
 Pawaret Leowanawat
 Darunee Soorukram
 Chutima Kuhakarn

Other Contributor(s)

Mahidol University

Abstract

© The Royal Society of Chemistry. Diverse 2-sulfonyl- and 2-thiocyanato-3-substituted quinolines were synthesized from o-alkynylisocyanobenzenes by nucleophilic addition of the respective sulfinate sodium salts and ammonium thiocyanate to the isocyanide moiety followed by cyclization. The salient features of the methodology include metal-free, ambient temperature and mild reaction conditions, ease of reagent handling, and broad functional group tolerance.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/45272

Collections

Scopus 2018