Publication: Influence of manganese substitution into the A-site of perovskite type Ca<inf>1-x</inf>Mn<inf>x</inf>TiO<inf>3</inf>ceramic
Issued Date
2011-09-01
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02728842
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2-s2.0-79960287229
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Mahidol University
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SCOPUS
Bibliographic Citation
Ceramics International. Vol.37, No.7 (2011), 2075-2079
Suggested Citation
Weeraphat Pon-On, Siwaporn Meejoo, Asiya Mehtar, I. Ming Tang Influence of manganese substitution into the A-site of perovskite type Ca<inf>1-x</inf>Mn<inf>x</inf>TiO<inf>3</inf>ceramic. Ceramics International. Vol.37, No.7 (2011), 2075-2079. doi:10.1016/j.ceramint.2011.05.071 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/11675
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Title
Influence of manganese substitution into the A-site of perovskite type Ca<inf>1-x</inf>Mn<inf>x</inf>TiO<inf>3</inf>ceramic
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Abstract
Ca 1-x Mn x TiO 3 (x = 0-1.0) perovskite ceramics were prepared by conventional solid state reaction. XRD was used to confirm the microcrystalline nature of the Ca 1-x Mn x TiO 3 crystals. For the x = 0 composition, the XRD patterns were those of a single orthorhombic perovskite while for x = 0.2-0.8, the XRD spectra were those of two orthorhombic perovskite phases: CaTiO 3 and MnTiO 3 . For x = 1, XRD pattern was that of the MnTiO 3 phase only. The morphology and particle size of the grains of the different composition were observed using SEM. The size of the particles increased from 0.2 μm to 2-3 μm as x increased from 0 to 0.6. The room temperature dielectric constant at the frequency of 110 kHz for the x = 0.2 and x = 1.0 ceramics were ∼3.41 × 10 4 and ∼4.99 × 10 3 , respectively. The ESR linewidth of samples increased with increasing manganese content due to the formation of magnetic cluster. Our ESR studies indicate that the manganese ions are in the Mn 4+ state. © 2011 Published by Elsevier Ltd and Techna Group S.r.l.