Development of a simultaneous measurement system of X-ray diffraction and Raman spectra: Application to structural study of crystalline-phase transitions of chain molecules
Journal of Polymer Science, Part B: Polymer Physics. Vol.40, No.6 (2002), 495-506
Suggested Citation
Kohji Tashiro, Sobiroh Kariyo, Akihito Nishimori, Takashi Fujii, Seishi Saragai, Shinsuke Nakamoto, Tatsuya Kawaguchi, Akikazu Maatsumoto, Orapin Rangsiman Development of a simultaneous measurement system of X-ray diffraction and Raman spectra: Application to structural study of crystalline-phase transitions of chain molecules. Journal of Polymer Science, Part B: Polymer Physics. Vol.40, No.6 (2002), 495-506. doi:10.1002/polb.10112 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/20133
Research Projects
Organizational Units
Authors
Journal Issue
Thesis
Title
Development of a simultaneous measurement system of X-ray diffraction and Raman spectra: Application to structural study of crystalline-phase transitions of chain molecules
A bench-top-type system for simultaneous measurement of X-ray diffraction and Raman spectra was developed to investigate structural changes in the phase transitions of chain molecules. A relationship between conformational disordering and rotational motion of molecular chains was detected by comparing two types of data. The structural change in the photoinduced solid-state polymerization of cis,cis-diethylmuconate single crystals was also studied. It was found that the molecular deformation of the polymer chains and lattice strain was induced in the early stage of polymerization reaction.
