Publication:
Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones

Issued Date

1983-01-01

Resource Type

Article

ISSN

00404039

DOI

10.1016/S0040-4039(00)81509-9

Other identifier(s)

2-s2.0-0000086269

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron Letters. Vol.24, No.7 (1983), 725-728

Suggested Citation

Vichai Reutrakul, Vatcharin Rukachaisirikul Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones. Tetrahedron Letters. Vol.24, No.7 (1983), 725-728. doi:10.1016/S0040-4039(00)81509-9 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/30447

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Title

Fluoromethyl phenyl sulfoxide: Highly convenient syntheses of vinyl fluorides and fluoromethylketones

Author(s)

Vichai Reutrakul
 Vatcharin Rukachaisirikul

Other Contributor(s)

Mahidol University

Abstract

Alkylation of lithio fluoromethyl phenyl sulfoxide 2 gave the alkylated products in high yields. Pyrolysis of the products led to vinyl fluorides in excellent yields. The reaction of 2 with carbonyl compounds led to the corresponding β-hydroxy-α-fluoromethyl phenyl sulfoxides. Pyrolysis of some of the sulfoxides gave fluoromethylketones in moderate yields. © 1983.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

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URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/30447

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Scopus 1969-1990