Publication: Oxiranyl remote anions from epoxy cinnamates and their application towards the synthesis of α,β-epoxy-γ-butyrolactones
| dc.contributor.author | Patpanat Sermmai | en_US |
| dc.contributor.author | Nopporn Ruangsupapichat | en_US |
| dc.contributor.author | Tienthong Thongpanchang | en_US |
| dc.contributor.other | Mahidol University | en_US |
| dc.date.accessioned | 2020-12-28T04:01:22Z | |
| dc.date.available | 2020-12-28T04:01:22Z | |
| dc.date.issued | 2020-12-10 | en_US |
| dc.description.abstract | © 2020 Elsevier Ltd A series of α,β-epoxy-γ-butyrolactones were synthesized in moderate yields via oxiranyl remote anions derived from epoxy cinnamate esters. The key synthetic step involved deprotonation of the β-position of α,β-epoxy cinnamate derivatives where the generated β-anion was stabilized by remote chelation from an ester group. The substitution reaction of the anion with a variety of ketones, followed by cyclization, readily furnished the desired substituted α,β-epoxy-γ-butyrolactones. | en_US |
| dc.identifier.citation | Tetrahedron Letters. Vol.61, No.50 (2020) | en_US |
| dc.identifier.doi | 10.1016/j.tetlet.2020.152609 | en_US |
| dc.identifier.issn | 18733581 | en_US |
| dc.identifier.issn | 00404039 | en_US |
| dc.identifier.other | 2-s2.0-85096084282 | en_US |
| dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/123456789/60381 | |
| dc.rights | Mahidol University | en_US |
| dc.rights.holder | SCOPUS | en_US |
| dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85096084282&origin=inward | en_US |
| dc.subject | Biochemistry, Genetics and Molecular Biology | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Oxiranyl remote anions from epoxy cinnamates and their application towards the synthesis of α,β-epoxy-γ-butyrolactones | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85096084282&origin=inward | en_US |