Publication: Pertosylated pillar[5]arene: Self-template assisted synthesis and supramolecular polymer formation
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Issued Date
2020-08-11
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ISSN
1364548X
13597345
13597345
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2-s2.0-85089165590
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Mahidol University
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SCOPUS
Bibliographic Citation
Chemical Communications. Vol.56, No.62 (2020), 8739-8742
Suggested Citation
Araya Ruengsuk, Korawit Khamphaijun, Puttipong Pananusorn, Andrew Docker, Jonggol Tantirungrotechai, Mongkol Sukwattanasinitt, David J. Harding, Thanthapatra Bunchuay Pertosylated pillar[5]arene: Self-template assisted synthesis and supramolecular polymer formation. Chemical Communications. Vol.56, No.62 (2020), 8739-8742. doi:10.1039/d0cc04005c Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/57790
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Title
Pertosylated pillar[5]arene: Self-template assisted synthesis and supramolecular polymer formation
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Abstract
© The Royal Society of Chemistry. A facile synthesis of decatosylate pillar[5]arene 1 is reported in excellent yield (>70%). The high yield is attributed to a self-template effect of the pendant tosylate arms. The X-ray crystal structure shows the formation of a linear supramolecular polymer, stabilised by intermolecular pillar[5]arene-tosylate inclusion complexes. These polymeric arrays persist in solution and form rod-like microfibril nanostructures evidenced by SEM. This journal is