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Tricarbonyliron complexes derived from dimethyl 1,3-butadiene-2,3-dicarboxylate: Formation of [Fe(CO)<inf>3</inf>]<inf>2</inf>-dimethyl 1,3-butadiene-2,3-dicarboxylate

1

Issued Date

1999-12-15

Resource Type

Article

ISSN

01082701

DOI

10.1107/S0108270199011695

Other identifier(s)

2-s2.0-0347333623

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Acta Crystallographica Section C: Crystal Structure Communications. Vol.55, No.12 (1999), 2007-2010

Suggested Citation

Palangpon Kongsaeree, Suthad Tanboriphan, Bongkoch Tarnchompoo, Yodhathai Thebtaranonth Tricarbonyliron complexes derived from dimethyl 1,3-butadiene-2,3-dicarboxylate: Formation of [Fe(CO)<inf>3</inf>]<inf>2</inf>-dimethyl 1,3-butadiene-2,3-dicarboxylate. Acta Crystallographica Section C: Crystal Structure Communications. Vol.55, No.12 (1999), 2007-2010. doi:10.1107/S0108270199011695 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/25322

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Title

Tricarbonyliron complexes derived from dimethyl 1,3-butadiene-2,3-dicarboxylate: Formation of [Fe(CO)<inf>3</inf>]<inf>2</inf>-dimethyl 1,3-butadiene-2,3-dicarboxylate

Author(s)

Palangpon Kongsaeree
 Suthad Tanboriphan
 Bongkoch Tarnchompoo
 Yodhathai Thebtaranonth

Other Contributor(s)

Mahidol University
 Thailand National Center for Genetic Engineering and Biotechnology

Abstract

Treatment of dimethyl 1,3-butadiene-2,3-dicarboxylate with Fe2(CO)9provided the corresponding tricarbonyl(η4-dimethyl 1,3-butadiene-2,3-dicarboxylatoO)iron, [Fe(C8H10O4)(CO)3], (II), as the main product and the novel μ-[(1,2-η,κO3:3,4-η,κO2)-dimethyl 1,3-butadiene-2,3-dicarboxylato]bis(tricarbonyliron), [Fe2-(C8H10O4)(CO)6], (III). In the crystal structure of (II), the electron-deficient butadiene complexes with one Fe(CO)3group, whereas in (III), the butadiene adopts an unusual conformation and forms a complex with two Fe(CO)3groups. In (III), each Fe atom possesses a trigonal bipyramidal geometry, with one olefinic bond and two carbonyl ligands occupying the basal positions, and the keto oxygen of the ester and the other carbonyl ligand occupying apical positions.

Keyword(s)

Biochemistry, Genetics and Molecular Biology

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https://repository.li.mahidol.ac.th/handle/123456789/25322

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