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Electrophilic difluoro(phenylthio)methylation: Generation, stability, and reactivity of α-fluorocarbocations

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dc.contributor.authorNolan M. Betterleyen_US
dc.contributor.authorPanida Surawatanawongen_US
dc.contributor.authorSamran Prabpaien_US
dc.contributor.authorPalangpon Kongsaereeen_US
dc.contributor.authorChutima Kuhakarnen_US
dc.contributor.authorManat Pohmakotren_US
dc.contributor.authorVichai Reutrakulen_US
dc.contributor.otherMahidol Universityen_US
dc.date.accessioned2018-10-19T04:34:07Z
dc.date.available2018-10-19T04:34:07Z
dc.date.issued2013-11-15en_US
dc.description.abstractElectrophilic difluoro(phenylthio)methylation of allylsilanes has been achieved using bromodifluoro(phenylthio)methane (PhSCF2Br) and silver hexafluoroantimonate (AgSbF6). The structural assignment and observation of α-fluorocarbocation were substantiated by NMR and theoretical calculations. Detailed mechanistic and electronic studies have provided a fundamental understanding of the reactivity and stability of the difluoro(phenylthio)methylium cation (PhSCF2+). © 2013 American Chemical Society.en_US
dc.identifier.citationOrganic Letters. Vol.15, No.22 (2013), 5666-5669en_US
dc.identifier.doi10.1021/ol402631ten_US
dc.identifier.issn15237052en_US
dc.identifier.issn15237060en_US
dc.identifier.other2-s2.0-84887968286en_US
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/20.500.14594/31164
dc.rightsMahidol Universityen_US
dc.rights.holderSCOPUSen_US
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84887968286&origin=inwarden_US
dc.subjectBiochemistry, Genetics and Molecular Biologyen_US
dc.subjectChemistryen_US
dc.titleElectrophilic difluoro(phenylthio)methylation: Generation, stability, and reactivity of α-fluorocarbocationsen_US
dc.typeArticleen_US
dspace.entity.typePublication
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84887968286&origin=inwarden_US

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