Publication:
Two protocols for the conversion of biphenol to binaphthol: Synthesis of diospyrol

Issued Date

2006-05-03

Resource Type

Article

ISSN

09365214

DOI

10.1055/s-2006-939075

Other identifier(s)

2-s2.0-33646548606

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Synlett. No.7 (2006), 1080-1084

Suggested Citation

Nopporn Thasana, Somchai Pisutjaroenpong, Somsak Ruchirawat Two protocols for the conversion of biphenol to binaphthol: Synthesis of diospyrol. Synlett. No.7 (2006), 1080-1084. doi:10.1055/s-2006-939075 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/23164

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Title

Two protocols for the conversion of biphenol to binaphthol: Synthesis of diospyrol

Author(s)

Nopporn Thasana
 Somchai Pisutjaroenpong
 Somsak Ruchirawat

Other Contributor(s)

Chulabhorn Research Institute
 The Institute of Science and Technology for Research and Development, Mahidol University

Abstract

The application of directed orthometallation (DoM), Fries rearrangement and transmetallation followed by allylation and cyclization is reported for the conversion of biphenol to binaphthol as a means for the synthesis of diospyrol. Furthermore, the same transformation can be accomplished by the reaction of the dienolate anion of an α,β-unsaturated amide with an aryne intermediate. © Georg Thieme Verlag Stuttgart.

Keyword(s)

Chemistry

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URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/23164

Collections

Scopus 2006-2010