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Cyclisation vs acylL migration OF α-allyl lactone dreived anion : Synthesis of spiro[4,5]dec-2-ene-1,6-diones

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dc.contributor.authorW. Jaivisuthunzaen_US
dc.contributor.authorB. Tarnchompooen_US
dc.contributor.authorC. Thebtaranonthen_US
dc.contributor.authorY. Thebtaranonthen_US
dc.contributor.otherMahidol Universityen_US
dc.contributor.otherThailand National Center for Genetic Engineering and Biotechnologyen_US
dc.date.accessioned2018-07-04T07:21:55Z
dc.date.available2018-07-04T07:21:55Z
dc.date.issued1996-04-29en_US
dc.description.abstractDirected by substituent R1, the α-allyl-γ-butyrolactone 9 either undergoes cyclisation to give the alcoholic cyclopentenone 12 or 1,2-acyl migration to give 13, when subjected to treatment with LDA in THF/TMEDA. An effective strategy to nullify this directive influence, and dictate cyclisation, is exemplified in a model synthesis of spiro[4,5]dec-2-ene-1,6-dione 19 by a one-pot tandem cyclisation - elimination process starting from 16. Copyright © 1996 Elsevier Science Ltd.en_US
dc.identifier.citationTetrahedron Letters. Vol.37, No.18 (1996), 3199-3202en_US
dc.identifier.doi10.1016/0040-4039(96)00494-7en_US
dc.identifier.issn00404039en_US
dc.identifier.other2-s2.0-0029997292en_US
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/20.500.14594/17543
dc.rightsMahidol Universityen_US
dc.rights.holderSCOPUSen_US
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0029997292&origin=inwarden_US
dc.subjectBiochemistry, Genetics and Molecular Biologyen_US
dc.subjectChemistryen_US
dc.subjectPharmacology, Toxicology and Pharmaceuticsen_US
dc.titleCyclisation vs acylL migration OF α-allyl lactone dreived anion : Synthesis of spiro[4,5]dec-2-ene-1,6-dionesen_US
dc.typeArticleen_US
dspace.entity.typePublication
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0029997292&origin=inwarden_US

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