Publication: Stereoselective synthesis of naturally occurring α-methylenebis-γ-butyrolactones: An application of novel oxiranyl "remote" anions
| dc.contributor.author | J. Lertvorachon | en_US |
| dc.contributor.author | Y. Thebtaranonth | en_US |
| dc.contributor.author | T. Thongpanchang | en_US |
| dc.contributor.author | P. Thongyoo | en_US |
| dc.contributor.other | Mahidol University | en_US |
| dc.date.accessioned | 2018-09-07T09:39:40Z | |
| dc.date.available | 2018-09-07T09:39:40Z | |
| dc.date.issued | 2001-06-29 | en_US |
| dc.description.abstract | Stereospecific deprotonation of the epoxy proton at the β-position of the α,β-epoxy esters 5 and 6 yielded oxiranyl "remote" anions 7 and 8, which could then be used for alkylation. The anions 7 and 8 underwent a consecutive aldol lactonization to give, respectively, epoxy lactones 11 and 13 with high stereoselectivity. Generation of the remote anions as well as their stereoselective reactions served as a new synthetic route to the naturally occurring α-methylenebis-γ-butyrolactones, 1. | en_US |
| dc.identifier.citation | Journal of Organic Chemistry. Vol.66, No.13 (2001), 4692-4694 | en_US |
| dc.identifier.doi | 10.1021/jo010259f | en_US |
| dc.identifier.issn | 00223263 | en_US |
| dc.identifier.other | 2-s2.0-0035967750 | en_US |
| dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/20.500.14594/26508 | |
| dc.rights | Mahidol University | en_US |
| dc.rights.holder | SCOPUS | en_US |
| dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0035967750&origin=inward | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Stereoselective synthesis of naturally occurring α-methylenebis-γ-butyrolactones: An application of novel oxiranyl "remote" anions | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0035967750&origin=inward | en_US |