Publication: Monomethylaluminum and dimethylaluminum pyrrolylaldiminates for the ring-opening polymerization of rac-lactide: Effects of ligand structure and coordination geometry
Issued Date
2014-01-21
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ISSN
14779234
14779226
14779226
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2-s2.0-84890503394
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Mahidol University
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SCOPUS
Bibliographic Citation
Dalton Transactions. Vol.43, No.3 (2014), 1348-1359
Suggested Citation
Sittichoke Tabthong, Tanin Nanok, Palangpon Kongsaeree, Samran Prabpai, Pimpa Hormnirun Monomethylaluminum and dimethylaluminum pyrrolylaldiminates for the ring-opening polymerization of rac-lactide: Effects of ligand structure and coordination geometry. Dalton Transactions. Vol.43, No.3 (2014), 1348-1359. doi:10.1039/c3dt52455h Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/33637
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Title
Monomethylaluminum and dimethylaluminum pyrrolylaldiminates for the ring-opening polymerization of rac-lactide: Effects of ligand structure and coordination geometry
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Abstract
Two series of aluminum alkyl complexes supported by pyrrolylaldiminate ligands, LAlMe2(1a-7a) and L2AlMe (1b-7b), were successfully synthesized and characterized by NMR spectroscopy and elemental analysis. Reactions of trimethylaluminum with the corresponding pyrrolylaldiminate ligands in the molar ratios of 1:1 and 1:2 yielded dimethylaluminum pyrrolylaldiminates (1a-7a) and monomethylaluminum pyrrolylaldiminates (1b-7b), respectively, in good yields. The structure of 3b, determined by single-crystal X-ray diffraction, displayed a distorted trigonal bipyramidal geometry with the τ value of 0.65. Upon addition of 1 equivalent of benzyl alcohol, all complexes promoted the living ring-opening polymerization of rac-lactide with a good control over molecular weights and polydispersities. Complexes 6a and 7a were found to efficiently mediate the immortal polymerization in the presence of excess equivalents of benzyl alcohol (up to 5 equivalents), as evidenced by the narrow PDI values and the good agreement between the experimental Mnvalues and monomer/benzyl alcohol ratios. The steric and electronic effects of the imine nitrogen substituents had a strong influence on the polymerization activities both in catalytic activity and polymer microstructure. The catalytic activity decreased as follows: 4-Me-C6H4(3) > C6H5(1) ≈ 4-F-C6H4(2) ≈ 2-Me-C6H4(5) > 4-OMe-C6H4(4) ≫ 2-tBu-C6H4(6) > adamantyl (7). In comparison, the catalytic activity of the monomethylaluminum complex is slightly higher than that of the dimethylaluminum counterpart. The polymerization of rac-lactide by 6b yielded heterotactically enriched polylactide (Pr= 0.60) whereas the isotactic-enriched polymer (Pm= 0.74) was obtained from 7b. © The Royal Society of Chemistry 2014.