Publication:
Condensed mode cooling for ethylene polymerization: Part II. the effect of different condensable comonomers and hydrogen on polymerization rate

Issued Date

2015-05-01

Resource Type

Article

ISSN

15213935
10221352

DOI

10.1002/macp.201500023

Other identifier(s)

2-s2.0-84929028611

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Macromolecular Chemistry and Physics. Vol.216, No.9 (2015), 985-995

Suggested Citation

Arash Alizadeh, Montree Namkajorn, Ekasith Somsook, Timothy F.L. McKenna Condensed mode cooling for ethylene polymerization: Part II. the effect of different condensable comonomers and hydrogen on polymerization rate. Macromolecular Chemistry and Physics. Vol.216, No.9 (2015), 985-995. doi:10.1002/macp.201500023 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/35752

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Title

Condensed mode cooling for ethylene polymerization: Part II. the effect of different condensable comonomers and hydrogen on polymerization rate

Author(s)

Arash Alizadeh
 Montree Namkajorn
 Ekasith Somsook
 Timothy F.L. McKenna

Other Contributor(s)

LCPP Laboratoire de Chimie et Procedes de Polymerisation
 Mahidol University

Abstract

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A systematic analysis methodology is proposed in order to be able to evaluate the role and the significance of the impact of the physical and chemical phenomena during the gas phase ethylene copolymerization in presence of 1-pentene and 1-hexene comonomers in the gas phase composition. In addition, the effect of inert n-hexane on the instantaneous rate of gas phase ethylene polymerization in the absence and presence of 1-hexene comonomer and hydrogen is investigated. This, in turn, provides a novel insight on the counter-effects of the physical and chemical phenomena taking place simultaneously during the gas phase processes for ethylene polymerization in the industrially relevant conditions.

Keyword(s)

Chemistry
 Materials Science

Availability

URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/35752

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Scopus 2011-2015