Publication:
Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane: A novel route to 3- acylfurans

Issued Date

1996-06-24

Resource Type

Article

ISSN

00404039

DOI

10.1016/0040-4039(96)00852-0

Other identifier(s)

2-s2.0-0030600152

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Tetrahedron Letters. Vol.37, No.26 (1996), 4585-4588

Suggested Citation

Manat Pohmakotr, Auntika Takampon Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane: A novel route to 3- acylfurans. Tetrahedron Letters. Vol.37, No.26 (1996), 4585-4588. doi:10.1016/0040-4039(96)00852-0 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/17541

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Title

Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane: A novel route to 3- acylfurans

Author(s)

Manat Pohmakotr
 Auntika Takampon

Other Contributor(s)

Mahidol University

Abstract

Destannylative acylation of 1-[(2-methoxyethoxy)methoxy]-2- (phenylsulfonyl)-2-(tributylstannyl)cyclopropane (1) provided dihydrofurans 5 in good yields, which upon treatment with BF3.OEt2in CH2Cl2led to the formation of 3-acylfurans 6 in moderate yields. The reaction was proposed to proceed via the intramolecular Prins-type reaction of the oxonium intermediate 7.

Keyword(s)

Biochemistry, Genetics and Molecular Biology
 Chemistry
 Pharmacology, Toxicology and Pharmaceutics

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URI

https://repository.li.mahidol.ac.th/handle/20.500.14594/17541

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Scopus 1991-2000