Publication: Comparison of the activities of C<inf>2</inf>N and BCNO towards Congo red degradation
Issued Date
2019-01-01
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02540584
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2-s2.0-85056168832
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Mahidol University
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SCOPUS
Bibliographic Citation
Materials Chemistry and Physics. Vol.221, (2019), 397-408
Suggested Citation
Roberto C. Dante, Pablo Martín-Ramos, Pedro Chamorro-Posada, Siwaporn Meejoo-Smith, José Vázquez-Cabo, Óscar Rubiños-López, Luis Lartundo-Rojas, Francisco M. Sánchez-Árevalo, Jirawat Trakulmututa, Dario Rutto, Siraprapha Deebansok, Assadawoot Srikhaow Comparison of the activities of C<inf>2</inf>N and BCNO towards Congo red degradation. Materials Chemistry and Physics. Vol.221, (2019), 397-408. doi:10.1016/j.matchemphys.2018.09.068 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/51184
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Title
Comparison of the activities of C<inf>2</inf>N and BCNO towards Congo red degradation
Abstract
© 2018 Elsevier B.V. An n-type organic carbon nitride semiconductor, C2N, was synthesized by the pyrolysis of uric acid, and its properties were investigated by scanning electron and transmission electron microscopies, X-ray powder diffraction, and vibrational, UV-visible and X-ray photoelectron spectroscopies. This novel material, composed of crystalline flakes, featured a broad absorption centered at 700 nm, possibly due to charge transfer, and a 2.49 eV band gap. Its catalytic performance was assessed for the treatment of effluents with the diazo dye Congo red, comparing it with that of boron carbon nitrogen oxide, BCNO. Both wide band gap semiconductors exhibited decolorizing activity in the dark, although the mechanisms were different and were not photocatalytic: BCNO was more effective towards the adsorption-coordination due to the presence of B-O, while C2N was effective towards the adsorption and the advancement of the oxidation reaction. Their kinetic constants (0.19 and 0.02 min−1 for BCNO and C2N, respectively) were comparable to those of intermetallic compounds studied for azo dyes degradation in dark conditions. In view of the high color removal efficiency (97% after 20 min) and good reusability of BCNO, this study suggests a potential application of this catalyst for wastewater treatment, alone or in combination with C2N.