Publication: C-H Activation and Palladium Migration within Biaryls under Heck Reaction Conditions
dc.contributor.author | Gunter Karig | en_US |
dc.contributor.author | Maria Teresa Moon | en_US |
dc.contributor.author | Nopporn Thasana | en_US |
dc.contributor.author | Timothy Gallagher | en_US |
dc.contributor.other | University of Bristol | en_US |
dc.contributor.other | Chulabhorn Research Institute | en_US |
dc.contributor.other | Mahidol University | en_US |
dc.date.accessioned | 2018-07-24T02:56:26Z | |
dc.date.available | 2018-07-24T02:56:26Z | |
dc.date.issued | 2002-09-05 | en_US |
dc.description.abstract | (Equation Presented) Biaryl bromides such as 1 (R=NO2, H, OMe) undergo the Heck reaction to give both the expected products 3 ("retention") as well as "crossover" products 4 derived from a migration of Pd and net transfer of reactivity from one aryl ring to the other. Under the conditions used, crossover is increasingly favored when electron-deficient arenes are involved. Crossover products derived from transfer onto the pyridine ring have also been observed. | en_US |
dc.identifier.citation | Organic Letters. Vol.4, No.18 (2002), 3115-3118 | en_US |
dc.identifier.doi | 10.1021/ol026426v | en_US |
dc.identifier.issn | 15237060 | en_US |
dc.identifier.other | 2-s2.0-0001651123 | en_US |
dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/20.500.14594/20043 | |
dc.rights | Mahidol University | en_US |
dc.rights.holder | SCOPUS | en_US |
dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0001651123&origin=inward | en_US |
dc.subject | Biochemistry, Genetics and Molecular Biology | en_US |
dc.subject | Chemistry | en_US |
dc.title | C-H Activation and Palladium Migration within Biaryls under Heck Reaction Conditions | en_US |
dc.type | Article | en_US |
dspace.entity.type | Publication | |
mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0001651123&origin=inward | en_US |