Publication:
Esterification of fatty acid catalyzed by hydrothermally stable propylsulfonic acidfunctionalized mesoporous silica SBA-15

Issued Date

2013-06-06

Resource Type

Article

ISSN

13473352
13458957

DOI

10.5650/jos.62.435

Other identifier(s)

2-s2.0-84878462801

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Journal of Oleo Science. Vol.62, No.6 (2013), 435-442

Suggested Citation

Win Win Mar, Ekasith Somsook Esterification of fatty acid catalyzed by hydrothermally stable propylsulfonic acidfunctionalized mesoporous silica SBA-15. Journal of Oleo Science. Vol.62, No.6 (2013), 435-442. doi:10.5650/jos.62.435 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/31471

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Title

Esterification of fatty acid catalyzed by hydrothermally stable propylsulfonic acidfunctionalized mesoporous silica SBA-15

Author(s)

Win Win Mar
 Ekasith Somsook

Other Contributor(s)

Mahidol University

Abstract

Propylsulfonic acid-functionalized mesoporous silica SBA-15 has been synthesized via one-step strategy at 130°C based on the co-condensation of TEOS and MPTMS in the presence of Pluronic 123 polymer and H2O2in HCl aqueous solution. The synthesized solid exhibited hydrothermal stability in boiling water without significant change in textural properties. The catalytic performance of the synthesized solid was studied in the esterification of oleic acid with methanol. The experimental results revealed that the large mesopore structures of SBA-15-PrSO3H solid synthesized at 130°C could favor a facile access of oleic acid to the acid sites, making the comparable activity to that of phenyl ethyl sulfonic acid functionalized silica and higher than that of dry amberlyst-15. ©2013 by Japan Oil Chemists' Society.

Keyword(s)

Chemical Engineering
 Chemistry

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https://repository.li.mahidol.ac.th/handle/20.500.14594/31471

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