Journal of the Chemical Society, Chemical Communications. No.20 (1988), 1382-1383
Suggested Citation
Chulabhorn Mahidol, Yongyut Pinyopronpanit, Shuleewan Radviroongit, Chachanat Thebtaranonth, Yodhathai Thebtaranonth 1,2-Carbonyl migration along the allylic framework: Synthesis of alkenylnaphthoquinones. Journal of the Chemical Society, Chemical Communications. No.20 (1988), 1382-1383. doi:10.1039/C39880001382 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/15496
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1,2-Carbonyl migration along the allylic framework: Synthesis of alkenylnaphthoquinones
Instead of undergoing a cyclopentenone annulation, the allylmalonate anion derived from the dicarboxylate (7) rearranges to vinylsuccinate (5), an application of which has led to a convenient synthesis of vinylnaphthoquinones (10).