Physical Chemistry Chemical Physics. Vol.2, No.4 (2000), 429-434
Suggested Citation
Anthony J. Stone, Yuthana Tantirungrotechai, A. David Buckingham The dielectric virial coefficient and model intermolecular potentials. Physical Chemistry Chemical Physics. Vol.2, No.4 (2000), 429-434. doi:10.1039/a905990c Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/25916
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The dielectric virial coefficient and model intermolecular potentials
The second dielectric virial coefficient for HCl has been computed over a range of temperatures using several model potentials, and a number of approximations have been tested. Several approximations made in earlier work are shown to lead to substantial errors in the computed dielectric virial coefficient. The dielectric virial coefficient is a sensitive test of model potentials, but the calculations need to be carried out accurately. Values are predicted for water, carbon monoxide, HF, HCN and FCH3.
