Manat Pohmakotr, Anusorn Seubsai, Pornthep Numeechai, Patoomratana Tuchinda A new strategy for the synthesis of (±)-Lupinine and (±)-epilupinine via cyclization of α-sulfinyl carbanions. Synthesis. No.11 (2008), 1733-1736. doi:10.1055/s-2008-1067027 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/19041
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A new strategy for the synthesis of (±)-Lupinine and (±)-epilupinine via cyclization of α-sulfinyl carbanions
(±)-Lupinine and (±)-epilupinine have been prepared starting from commercially available δ-valerolactam. The synthetic route involves the advantages of the cyclization based on α-sulfmyl carbanions.