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Highly diastereoselective synthesis of β-carboxy-γ-lactams and their ethyl esters via Sc(OTf)<inf>3</inf>-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with imines

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dc.contributor.authorManat Pohmakotren_US
dc.contributor.authorNattawut Yotapanen_US
dc.contributor.authorPatoomratana Tuchindaen_US
dc.contributor.authorChutima Kuhakarnen_US
dc.contributor.authorVichai Reutrakulen_US
dc.contributor.otherMahidol Universityen_US
dc.date.accessioned2018-08-24T01:46:29Z
dc.date.available2018-08-24T01:46:29Z
dc.date.issued2007-06-22en_US
dc.description.abstract(Chemical Equation Presented) Functionalized γ-lactams are found to be crucial intermediates in the synthesis of biologically important natural products. We herein described a highly diastereoselective synthesis of β-carboxy-γ-lactams and their ethyl ester derivatives, in high yields with high diastereomeric ratio, via the Mukaiyama-aldol type reaction of 2,5-bis(trimethysilyloxy)furan with imines, employing Sc(OTf)3 as a catalyst. © 2007 American Chemical Society.en_US
dc.identifier.citationJournal of Organic Chemistry. Vol.72, No.13 (2007), 5016-5019en_US
dc.identifier.doi10.1021/jo070533ren_US
dc.identifier.issn00223263en_US
dc.identifier.other2-s2.0-34250885710en_US
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/20.500.14594/24348
dc.rightsMahidol Universityen_US
dc.rights.holderSCOPUSen_US
dc.source.urihttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34250885710&origin=inwarden_US
dc.subjectChemistryen_US
dc.titleHighly diastereoselective synthesis of β-carboxy-γ-lactams and their ethyl esters via Sc(OTf)<inf>3</inf>-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with iminesen_US
dc.typeArticleen_US
dspace.entity.typePublication
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=34250885710&origin=inwarden_US

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