Publication: Statistically guided synthesis of MoV-based mixed-oxide catalysts for ethane partial oxidation
Issued Date
2018-09-02
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ISSN
20734344
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2-s2.0-85053774941
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Mahidol University
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SCOPUS
Bibliographic Citation
Catalysts. Vol.8, No.9 (2018)
Suggested Citation
Juan D. Jimenez, Kathleen Mingle, Teeraya Bureerug, Cun Wen, Jochen Lauterbach Statistically guided synthesis of MoV-based mixed-oxide catalysts for ethane partial oxidation. Catalysts. Vol.8, No.9 (2018). doi:10.3390/catal8090370 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/45420
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Title
Statistically guided synthesis of MoV-based mixed-oxide catalysts for ethane partial oxidation
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Abstract
© 2018 by the authors. Licensee MDPI, Basel, Switzerland. The catalytic performance of Mo8V2Nb1-based mixed-oxide catalysts for ethane partial oxidation is highly sensitive to the doping of elements with redox and acid functionality. Specifically, control over product distributions to ethylene and acetic acid can be afforded via the specific pairing of redox elements (Pd, Ni, Ti) and acid elements (K, Cs, Te) and the levels at which these elements are doped. The redox element, acid element, redox/acid ratio, and dopant/host ratio were investigated using a three-level, four-factor factorial screening design to establish relationships between catalyst composition, structure, and product distribution for ethane partial oxidation. Results show that the balance between redox and acid functionality and overall dopant level is important for maximizing the formation of each product while maintaining the structural integrity of the host metal oxide. Overall, ethylene yield was maximized for a Mo8V2Nb1Ni0.0025Te0.5 composition, while acetic acid yield was maximized for a Mo8V2Nb1Ti0.005 Te1 catalyst.