Publication: Solid–state Synthesis of Polyhedral Oligomeric Silsesquioxane-Supported N-Heterocyclic Carbenes/Imidazolium salts on Palladium Nanoparticles: Highly Active and Recyclable Catalyst
| dc.contributor.author | Sudip Mohapatra | en_US |
| dc.contributor.author | Thanawat Chaiprasert | en_US |
| dc.contributor.author | Rapheepraew Sodkhomkhum | en_US |
| dc.contributor.author | Rungthip Kunthom | en_US |
| dc.contributor.author | Sasikarn Hanprasit | en_US |
| dc.contributor.author | Preeyanuch Sangtrirutnugul | en_US |
| dc.contributor.author | Vuthichai Ervithayasuporn | en_US |
| dc.contributor.other | Mahidol University | en_US |
| dc.date.accessioned | 2018-12-11T02:35:22Z | |
| dc.date.accessioned | 2019-03-14T08:04:27Z | |
| dc.date.available | 2018-12-11T02:35:22Z | |
| dc.date.available | 2019-03-14T08:04:27Z | |
| dc.date.issued | 2016-01-01 | en_US |
| dc.description.abstract | © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim We describe a novel and green synthetic methodology for the fabrication of polyhedral oligomeric silsesquioxane-supported N-heterocyclic carbenes/imidazolium salts on palladium(II) complexes; Pd(II)-MPIm-POSS (1) composite by solid-state annealing between Pd(OAc)2 and octakis(3-(1-methylimidazolium)propyl) octasilsesquioxane without added base. Subsequently, arylboronic acid based in situ or ex situ reduction of 1 in aqueous ethanol produces polyhedral oligomeric silsesquioxane-supported N-heterocyclic carbenes/imidazolium salts on palladium nanoparticles; Pd(0)-nano-POSS (2) composite, consisting of monodispersed and N-heterocyclic carbene (NHC) stabilized Pd nanoparticles of very small size (3.0 ± 1.5 nm). Nanocatalyst 2 is a highly efficient and easily recyclable homogeneous catalyst for Suzuki-Miyaura cross-coupling reactions with TOF up to 1670 h−1. | en_US |
| dc.identifier.citation | ChemistrySelect. Vol.1, No.16 (2016), 5353-5357 | en_US |
| dc.identifier.doi | 10.1002/slct.201600878 | en_US |
| dc.identifier.issn | 23656549 | en_US |
| dc.identifier.other | 2-s2.0-85017415789 | en_US |
| dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/20.500.14594/43395 | |
| dc.rights | Mahidol University | en_US |
| dc.rights.holder | SCOPUS | en_US |
| dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85017415789&origin=inward | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Solid–state Synthesis of Polyhedral Oligomeric Silsesquioxane-Supported N-Heterocyclic Carbenes/Imidazolium salts on Palladium Nanoparticles: Highly Active and Recyclable Catalyst | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85017415789&origin=inward | en_US |