Phosphazene-catalyzed regioselective condensation of allyl thioethers with aldehydes: A rapid approach to 1,3-dienyl sulfides, -sulfoxides, and -sulfones
| dc.contributor.author | Phae-Nok S. | |
| dc.contributor.author | Kuhakarn C. | |
| dc.contributor.author | Leowanawat P. | |
| dc.contributor.author | Reutrakul V. | |
| dc.contributor.author | Soorukram D. | |
| dc.contributor.correspondence | Phae-Nok S. | |
| dc.contributor.other | Mahidol University | |
| dc.date.accessioned | 2024-02-21T18:06:40Z | |
| dc.date.available | 2024-02-21T18:06:40Z | |
| dc.date.issued | 2024-01-01 | |
| dc.description.abstract | Phosphazene-catalyzed regioselective condensation of allyl thioethers with aldehydes was investigated. Upon treatment of allyl thioethers with P 4 -t-Bu, allyl thioether anions were generated and rapidly reacted with aromatic aldehydes, leading to 1,3-dienyl sulfides in good yields with high regioselectivity. This finding provides an alternative preparation of allyl thioether anions in a regioselective manner. In addition, chemoselective transformation of 1,3-dienyl sulfides to provide the corresponding 1,3-dienyl sulfoxides or 1,3-dienyl sulfones was also demonstrated. | |
| dc.identifier.citation | Synthesis (Germany) (2024) | |
| dc.identifier.doi | 10.1055/a-2259-5395 | |
| dc.identifier.eissn | 1437210X | |
| dc.identifier.issn | 00397881 | |
| dc.identifier.scopus | 2-s2.0-85184910883 | |
| dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/20.500.14594/97289 | |
| dc.rights.holder | SCOPUS | |
| dc.subject | Chemical Engineering | |
| dc.subject | Chemistry | |
| dc.title | Phosphazene-catalyzed regioselective condensation of allyl thioethers with aldehydes: A rapid approach to 1,3-dienyl sulfides, -sulfoxides, and -sulfones | |
| dc.type | Article | |
| mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85184910883&origin=inward | |
| oaire.citation.title | Synthesis (Germany) | |
| oairecerif.author.affiliation | Mahidol University |