Ruthenium-NHC complex-catalyzed P(iii)-directed C-H borylation of arylphosphines
Issued Date
2022-10-04
Resource Type
ISSN
13597345
eISSN
1364548X
Scopus ID
2-s2.0-85140848014
Pubmed ID
36218342
Journal Title
Chemical Communications
Volume
58
Issue
86
Start Page
12082
End Page
12085
Rights Holder(s)
SCOPUS
Bibliographic Citation
Chemical Communications Vol.58 No.86 (2022) , 12082-12085
Suggested Citation
Thongpaen J., Manguin R., Kittikool T., Camy A., Roisnel T., Dorcet V., Yotphan S., Canac Y., Mauduit M., Baslé O. Ruthenium-NHC complex-catalyzed P(iii)-directed C-H borylation of arylphosphines. Chemical Communications Vol.58 No.86 (2022) , 12082-12085. 12085. doi:10.1039/d2cc03909e Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/84046
Title
Ruthenium-NHC complex-catalyzed P(iii)-directed C-H borylation of arylphosphines
Other Contributor(s)
Abstract
(NHC)(arene)Ru(ii) complexes with bidentate LX-type NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. The strong coordination of the NHC carboxylate ligand and the labile character of the arene ligand are highlighted. These unprecedented Ru(ii) complexes demonstrated efficient catalytic activities in the selective P(iii)-directed C-H borylation at the ortho position of arylphosphines, representing the first report of the use of a ruthenium-NHC based catalyst in C-H borylation.