Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation

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dc.contributor.authorManguin R.
dc.contributor.authorGaliana-Cameo M.
dc.contributor.authorKittikool T.
dc.contributor.authorBarthes C.
dc.contributor.authorThongpaen J.
dc.contributor.authorBancal E.
dc.contributor.authorMallet-Ladeira S.
dc.contributor.authorYotphan S.
dc.contributor.authorCastarlenas R.
dc.contributor.authorMauduit M.
dc.contributor.authorSortais J.B.
dc.contributor.authorBaslé O.
dc.contributor.otherMahidol University
dc.date.accessioned2023-05-19T07:36:59Z
dc.date.available2023-05-19T07:36:59Z
dc.date.issued2023-03-17
dc.description.abstractA series of (NHC)(cod)Ir(i) complexes bearing NHC-carboxylate ligands were efficiently synthesized and fully characterized. Their solid-state structures confirmed the bidentate coordination mode of these LX-type NHC ligands. These unprecedented iridium(i) complexes demonstrated efficient catalytic activities in dehydrogenative directed C-H silylation of arenes, and allowed for excellent ortho-selectivity control with aromatic silylating agents.
dc.identifier.citationChemical Communications Vol.59 No.28 (2023) , 4193-4196
dc.identifier.doi10.1039/d2cc06865f
dc.identifier.eissn1364548X
dc.identifier.issn13597345
dc.identifier.pmid36942515
dc.identifier.scopus2-s2.0-85152173915
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/20.500.14594/81704
dc.rights.holderSCOPUS
dc.subjectChemical Engineering
dc.titleIridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation
dc.typeArticle
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85152173915&origin=inward
oaire.citation.endPage4196
oaire.citation.issue28
oaire.citation.startPage4193
oaire.citation.titleChemical Communications
oaire.citation.volume59
oairecerif.author.affiliationInstitut des Sciences Chimiques de Rennes
oairecerif.author.affiliationUniversité Toulouse III - Paul Sabatier
oairecerif.author.affiliationUniversidad de Zaragoza
oairecerif.author.affiliationMahidol University

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