A study of the addition reaction of photosensitive acid onto epoxidised liquid natural rubber (ELNR) and its photosensitivity
2
Issued Date
2023
Copyright Date
1993
Language
eng
File Type
application/pdf
No. of Pages/File Size
x, 107 leaves : ill.
Access Rights
restricted access
Rights Holder(s)
Mahidol University
Bibliographic Citation
Thesis (M.Sc. (Polymer Science))--Mahidol University, 1993
Suggested Citation
Chantima Deeprasertkul A study of the addition reaction of photosensitive acid onto epoxidised liquid natural rubber (ELNR) and its photosensitivity. Thesis (M.Sc. (Polymer Science))--Mahidol University, 1993. Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/90537
Title
A study of the addition reaction of photosensitive acid onto epoxidised liquid natural rubber (ELNR) and its photosensitivity
Alternative Title(s)
การศึกษาปฏิกิริยาการเพิ่มเข้าไปของกรดที่ไวต่อแสงกับยางธรรมชาติเหลวอีพอกซิไดส์และคุณสมบัติทางแสงของสารที่เตรียมได้
Author(s)
Advisor(s)
Abstract
Epoxidised liquid natural rubber (ELNR) was prepared by depolymerization of natural rubber in latex phase by using phenylhydrazine/oxygen system, followed by in-situ peroxyformic acid epoxidation. The study of addition reaction of photosensitive acid; acrylic acid, methacrylic acid and cinnamic acid onto ELNR has been carried out into 2 systems: at high temperature and at room temperature. The evolution of the reaction was followed by determination of the residual acid at different time by potentiometric titration or IR spectroscopy. It was found that type and concentration of catalysts, type and concentration of acids and temperature affected the rate of the addition reaction and %conversion. Acrylic acid gave the best result in both cases. The photosensitivity of the ELNR grafted with the photosensitive acids in the presence or absence of benzophenone acted as photo initiator under UV irradiation were studied by IR and UV spectroscopic methods. It was found that benzophenone accelerated the photo crosslinking reaction. Physical properties of the cured films such as adhesion and hardness were also investigated.
Degree Name
Master of Science
Degree Level
Master's degree
Degree Department
Faculty of Science
Degree Discipline
Polymer Science
Degree Grantor(s)
Mahidol University