Pillar[4]arene[1]thioarenes: Synthesis and Host-Guest Binding Properties
1
Issued Date
2022-09-01
Resource Type
ISSN
09365214
eISSN
14372096
Scopus ID
2-s2.0-85129415734
Journal Title
Synlett
Volume
33
Issue
14
Start Page
1357
End Page
1362
Rights Holder(s)
SCOPUS
Bibliographic Citation
Synlett Vol.33 No.14 (2022) , 1357-1362
Suggested Citation
Khanthong A., Khamphaijun K., Ruengsuk A., Docker A., Limpanuparb T., Tantirungrotechai J., Bunchuay T. Pillar[4]arene[1]thioarenes: Synthesis and Host-Guest Binding Properties. Synlett Vol.33 No.14 (2022) , 1357-1362. 1362. doi:10.1055/a-1806-5999 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/84168
Title
Pillar[4]arene[1]thioarenes: Synthesis and Host-Guest Binding Properties
Author's Affiliation
Other Contributor(s)
Abstract
The synthesis and characterization of a novel class of pillar[4]arene[1]thioarenes (P[4]A[1]SMe) are reported. An oxidation thionation strategy was used to replace a single dialkoxybenzene panel in the parent pillar[5]arene. 1H NMR spectroscopic titration experiments, supported by density functional theory computational studies, revealed that P[4]A[1]SMe show starkly modulated host guest binding properties for electron-deficient aliphatic guests.