Electro-oxidative Methylation of 2-Isocyanobiaryls Using N,N-dimethylformamide (DMF) as Carbon Source: Synthesis of 6-Methylphenanthridines

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dc.contributor.authorLa-ongthong K.
dc.contributor.authorChantarojsiri T.
dc.contributor.authorSoorukram D.
dc.contributor.authorLeowanawat P.
dc.contributor.authorReutrakul V.
dc.contributor.authorKuhakarn C.
dc.contributor.correspondenceLa-ongthong K.
dc.contributor.otherMahidol University
dc.date.accessioned2024-04-18T18:09:46Z
dc.date.available2024-04-18T18:09:46Z
dc.date.issued2024-01-01
dc.description.abstractA benign electrochemical method to access 6-methylphenanthridines from 2-isocyanobiaryls using N,N-dimethylformamide (DMF) as a methyl source is reported. The protocol operates at ambient temperature without the need for harmful methylating reagents. Mechanistic studies suggested that DMF delivered a methylene synthon, followed by reduction at the cathode and tautomerization. The method offers environmental benefits by avoiding metal-based reagents and harsh conditions.
dc.identifier.citationChemistry - An Asian Journal (2024)
dc.identifier.doi10.1002/asia.202400176
dc.identifier.eissn1861471X
dc.identifier.issn18614728
dc.identifier.scopus2-s2.0-85189970995
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/123456789/98024
dc.rights.holderSCOPUS
dc.subjectChemistry
dc.subjectBiochemistry, Genetics and Molecular Biology
dc.titleElectro-oxidative Methylation of 2-Isocyanobiaryls Using N,N-dimethylformamide (DMF) as Carbon Source: Synthesis of 6-Methylphenanthridines
dc.typeArticle
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85189970995&origin=inward
oaire.citation.titleChemistry - An Asian Journal
oairecerif.author.affiliationMahidol University

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