Chain-length-dependent reactivity of alkenyl phosphates in ruthenium-catalyzed cross-metathesis

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dc.contributor.authorPontavatchai A.
dc.contributor.authorSchwedtmann K.
dc.contributor.authorRoyla P.
dc.contributor.authorSchwedtmann K.
dc.contributor.authorKhamnaen T.
dc.contributor.authorSchwarzenbolz U.
dc.contributor.authorHenle T.
dc.contributor.authorSomsook E.
dc.contributor.authorWeigand J.J.
dc.contributor.correspondencePontavatchai A.
dc.contributor.otherMahidol University
dc.date.accessioned2025-12-11T18:07:53Z
dc.date.available2025-12-11T18:07:53Z
dc.date.issued2025-01-01
dc.description.abstractWe report a chain-length-dependent reactivity pattern in the cross-metathesis of alkenyl phosphates catalyzed by the second-generation Grubbs catalyst (GII). While vinyl phosphates undergo unproductive decomposition to generate a ruthenium-carbide complex, extending the alkyl spacer restores productive cross-metathesis. DFT studies rationalize this transformation to occur via a proton-coupled phosphate elimination mechanism.
dc.identifier.citationChemical Communications (2025)
dc.identifier.doi10.1039/d5cc05790f
dc.identifier.eissn1364548X
dc.identifier.issn13597345
dc.identifier.scopus2-s2.0-105023555872
dc.identifier.urihttps://repository.li.mahidol.ac.th/handle/123456789/113457
dc.rights.holderSCOPUS
dc.subjectMaterials Science
dc.subjectChemical Engineering
dc.subjectChemistry
dc.titleChain-length-dependent reactivity of alkenyl phosphates in ruthenium-catalyzed cross-metathesis
dc.typeArticle
mu.datasource.scopushttps://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105023555872&origin=inward
oaire.citation.titleChemical Communications
oairecerif.author.affiliationTechnische Universität Dresden
oairecerif.author.affiliationFaculty of Science, Mahidol University
oairecerif.author.affiliationSCG Chemicals Co., Ltd.

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