Constructing Ni-Pt Bimetallic Catalysts for Catalytic Hydrogenation and Rearrangement of Furfural into Cyclopentanone with Insight in H/D Exchange by D<inf>2</inf>O Labeling
Issued Date
2024-01-01
Resource Type
eISSN
24701343
Scopus ID
2-s2.0-85196908593
Journal Title
ACS Omega
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SCOPUS
Bibliographic Citation
ACS Omega (2024)
Suggested Citation
Kittisabhorn A., Ahmed I., Pornputtapitak W., Ratchahat S., Chaiwat W., Koo-Amornpattana W., Klysubun W., Limphirat W., Assabumrungrat S., Srifa A. Constructing Ni-Pt Bimetallic Catalysts for Catalytic Hydrogenation and Rearrangement of Furfural into Cyclopentanone with Insight in H/D Exchange by D<inf>2</inf>O Labeling. ACS Omega (2024). doi:10.1021/acsomega.4c02827 Retrieved from: https://repository.li.mahidol.ac.th/handle/20.500.14594/99260
Title
Constructing Ni-Pt Bimetallic Catalysts for Catalytic Hydrogenation and Rearrangement of Furfural into Cyclopentanone with Insight in H/D Exchange by D<inf>2</inf>O Labeling
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Abstract
Developing a metallic catalyst for converting furfural (FAL) to highly valuable products such as cyclopentanone (CPO) is important for fine chemical synthesis by the efficient utilization of biomass resources. The presence of diverse unsaturated carbon atoms in FAL and the rearrangement of oxygen atoms hinder the production of CPO. We developed an optimal nickel (Ni)-to-platinum (Pt) molar ratio (1:0.007) for a bimetallic Ni-Pt/alumina (Al2O3) catalyst with a low Pt loading via an impregnation method to efficiently catalyze the selective hydrogenation of FAL in an aqueous solution to form CPO. The comprehensive characterizations by X-ray diffraction and X-ray absorption near edge structure analyses elucidated the formation of Ni0/Pt0 and Ni2+/Pt4+ after reduction by H2. The addition of a low amount of the Pt-Ni/Al2O3 catalyst resulted in an alleviation of H2 reduction behavior detected by hydrogen temperature-programmed reduction, accompanied by low H2 desorption ability observed by hydrogen temperature-programmed desorption. The catalytic activity of Ni-Pt/Al2O3 was higher than those of Ni/Al2O3 and Pt/Al2O3 catalysts. The maximum CPO yield was 66% with 93% FAL conversion under the optimized conditions (160 °C, 20 bar of H2 pressure, and 2 h). Isotopic deuterium oxide (D2O) labeling revealed the transfer of deuterium (D) atoms from D2O to the intermediates and products during hydrogenation and rearrangement, which confirmed that water was a medium for rearrangement and the source of hydrogen for the reaction. This study developed an efficient catalyst for the catalytic hydrogenation and ring rearrangement of FAL into CPO.