Publication: Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
Issued Date
2018-08-01
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21935807
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2-s2.0-85051440073
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Mahidol University
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SCOPUS
Bibliographic Citation
Asian Journal of Organic Chemistry. Vol.7, No.8 (2018), 1642-1647
Suggested Citation
Nolan M. Betterley, Sutthichat Kerdphon, Suppisak Chaturonrutsamee, Sopanat Kongsriprapan, Panida Surawatanawong, Darunee Soorukram, Manat Pohmakotr, Pher G. Andersson, Vichai Reutrakul, Chutima Kuhakarn Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane. Asian Journal of Organic Chemistry. Vol.7, No.8 (2018), 1642-1647. doi:10.1002/ajoc.201800313 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/45485
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Title
Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
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Abstract
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Bismuth(III) trifluoromethanesulfonate [Bi(OTf)3] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has been developed. The active formylating species was generated via C−F bond cleavage and was characterized to be a bis(phenylsulfanyl)methyl cation by experimental and computational 1H and 13C NMR.