Publication: Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane
| dc.contributor.author | Nolan M. Betterley | en_US |
| dc.contributor.author | Sutthichat Kerdphon | en_US |
| dc.contributor.author | Suppisak Chaturonrutsamee | en_US |
| dc.contributor.author | Sopanat Kongsriprapan | en_US |
| dc.contributor.author | Panida Surawatanawong | en_US |
| dc.contributor.author | Darunee Soorukram | en_US |
| dc.contributor.author | Manat Pohmakotr | en_US |
| dc.contributor.author | Pher G. Andersson | en_US |
| dc.contributor.author | Vichai Reutrakul | en_US |
| dc.contributor.author | Chutima Kuhakarn | en_US |
| dc.contributor.other | Kasetsart University | en_US |
| dc.contributor.other | Mahidol University | en_US |
| dc.contributor.other | Arrhenius Laboratory | en_US |
| dc.contributor.other | International Laboratories Corp. | en_US |
| dc.date.accessioned | 2019-08-23T10:49:26Z | |
| dc.date.available | 2019-08-23T10:49:26Z | |
| dc.date.issued | 2018-08-01 | en_US |
| dc.description.abstract | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Bismuth(III) trifluoromethanesulfonate [Bi(OTf)3] mediated mild electrophilic aromatic formylation utilizing difluoro(phenylsulfanyl)methane (PhSCF2H) as a formylating agent in hexafluoro-2-propanol (HFIP) as a recyclable ionizing solvent has been developed. The active formylating species was generated via C−F bond cleavage and was characterized to be a bis(phenylsulfanyl)methyl cation by experimental and computational 1H and 13C NMR. | en_US |
| dc.identifier.citation | Asian Journal of Organic Chemistry. Vol.7, No.8 (2018), 1642-1647 | en_US |
| dc.identifier.doi | 10.1002/ajoc.201800313 | en_US |
| dc.identifier.issn | 21935807 | en_US |
| dc.identifier.other | 2-s2.0-85051440073 | en_US |
| dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/123456789/45485 | |
| dc.rights | Mahidol University | en_US |
| dc.rights.holder | SCOPUS | en_US |
| dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85051440073&origin=inward | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Bi(OTf)<inf>3</inf> Enabled C-F Bond Cleavage in HFIP: Electrophilic Aromatic Formylation with Difluoro(phenylsulfanyl)methane | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85051440073&origin=inward | en_US |