Publication: Metal-Free Direct C–H Thiolation and Thiocyanation of Pyrazolones
| dc.contributor.author | Tanakorn Kittikool | en_US |
| dc.contributor.author | Sirilata Yotphan | en_US |
| dc.contributor.other | Mahidol University | en_US |
| dc.date.accessioned | 2020-03-26T04:38:15Z | |
| dc.date.available | 2020-03-26T04:38:15Z | |
| dc.date.issued | 2020-02-28 | en_US |
| dc.description.abstract | © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Metal-free approach for direct C–H thiolation and thiocyanation of N-substituted pyrazolones with disulfides and thiocyanate salts, respectively, are developed. These reactions allow the C–S bond coupling to proceed effectively under mild conditions, providing useful and convenient methods for preparation of a series of 4-thio-substituted pyrazolone analogues, which have potential applications in organic, medicinal and material chemistry. Preliminary mechanistic investigation suggested that radical processes are likely to involve in these transformations. | en_US |
| dc.identifier.citation | European Journal of Organic Chemistry. Vol.2020, No.8 (2020), 961-970 | en_US |
| dc.identifier.doi | 10.1002/ejoc.201901770 | en_US |
| dc.identifier.issn | 10990690 | en_US |
| dc.identifier.issn | 1434193X | en_US |
| dc.identifier.other | 2-s2.0-85079150929 | en_US |
| dc.identifier.uri | https://repository.li.mahidol.ac.th/handle/20.500.14594/53640 | |
| dc.rights | Mahidol University | en_US |
| dc.rights.holder | SCOPUS | en_US |
| dc.source.uri | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85079150929&origin=inward | en_US |
| dc.subject | Chemistry | en_US |
| dc.title | Metal-Free Direct C–H Thiolation and Thiocyanation of Pyrazolones | en_US |
| dc.type | Article | en_US |
| dspace.entity.type | Publication | |
| mu.datasource.scopus | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85079150929&origin=inward | en_US |