Publication:
Difluorophenylsulfanylmethyl radical and difluoromethylene diradical synthons: gem-difluoromethylene building block

1

Issued Date

2004-10-01

Resource Type

Article

ISSN

00223263

DOI

10.1021/jo0489768

Other identifier(s)

2-s2.0-4644302716

Rights

Mahidol University

Rights Holder(s)

SCOPUS

Bibliographic Citation

Journal of Organic Chemistry. Vol.69, No.20 (2004), 6913-6915

Suggested Citation

Vichai Reutrakul, Thanchanok Thongpaisanwong, Patoomratana Tuchinda, Chutima Kuhakarn, Manat Pohmakotr Difluorophenylsulfanylmethyl radical and difluoromethylene diradical synthons: gem-difluoromethylene building block. Journal of Organic Chemistry. Vol.69, No.20 (2004), 6913-6915. doi:10.1021/jo0489768 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/21268

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Title

Difluorophenylsulfanylmethyl radical and difluoromethylene diradical synthons: gem-difluoromethylene building block

Author(s)

Vichai Reutrakul
 Thanchanok Thongpaisanwong
 Patoomratana Tuchinda
 Chutima Kuhakarn
 Manat Pohmakotr

Other Contributor(s)

Mahidol University

Abstract

Bromodifluorophenylsulfanylmethane has been demonstrated to be a highly versatile gem-difluoromethylene (CF2) building block via the reaction of difluorophenylsulfanylmethyl radical with olefins. gem-Difluoroalkenes and products containing a midchain CF2 group and with manipulatable functionality can be readily synthesized. The first example of a gem-difluoromethylene radical synthon is also reported.

Keyword(s)

Chemistry

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URI

https://repository.li.mahidol.ac.th/handle/123456789/21268

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Scopus 2001-2005