Publication: Synthesis and thermal decomposition of cadmium dithiocarbamate complexes
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Issued Date
2006-05-01
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ISSN
0167577X
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2-s2.0-31644447422
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Mahidol University
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SCOPUS
Bibliographic Citation
Materials Letters. Vol.60, No.9-10 (2006), 1161-1165
Suggested Citation
Nirawan Thammakan, Ekasith Somsook Synthesis and thermal decomposition of cadmium dithiocarbamate complexes. Materials Letters. Vol.60, No.9-10 (2006), 1161-1165. doi:10.1016/j.matlet.2005.10.107 Retrieved from: https://repository.li.mahidol.ac.th/handle/123456789/23241
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Title
Synthesis and thermal decomposition of cadmium dithiocarbamate complexes
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Abstract
Cadmium(II) complexes of new polydentate dithiocarbamates with benzyl or methylferrocene as substituents have been prepared. The IR spectra of the complexes suggested a bidentate coordination of dithiocarbamate ligands to the cadmium ion. The thermal properties of cadmium complexes were studied by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Pyrolysis of cadmium complexes was further carried out at 700 °C and the products were characterized by powder X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). The pyrolysis of cadmium methylferrocene complex produced a product with nanofibers. © 2005 Elsevier B.V. All rights reserved.